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YAMATO Masayuki
Department Graduate School of Medical Science, Graduate School of Medical Science Position Professor |
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| Article types | Original article |
| Language | English |
| Peer review | Peer reviewed |
| Title | Thermo-responsive polymer brushes as intelligent biointerfaces: preparation via ATRP and characterization. |
| Journal | Formal name：Macromolecular bioscience Abbreviation：Macromol Biosci ISSN code：(1616-5195)1616-5187(Linking) |
| Domestic / Foregin | Foregin |
| Publisher | Wiley |
| Volume, Issue, Page | 11(3),pp.400-409 |
| Author and coauthor | Nagase Kenichi†, Watanabe Minami, Kikuchi Akihiko, Yamato Masayuki, Okano Teruo* |
| Publication date | 2011/03 |
| Summary | PIPAAm-brush grafted glass substrates with various graft densities and chain lengths were prepared via surface-initiated ATRP. Temperature-dependent physicochemical properties of the surfaces were characterized by means of ATR/FT-IR spectroscopy, XPS, AFM, and contact angle measurements. ATRP conditions influence the amount of grafted PIPAAm and the surface wettability and roughness of the substrate. Fibronectin adsorption and EC adhesion increased with decreasing density of PIPAAm brushes. EC adhesion was diminished with increasing PIPAAm graft length. Thus, the preparation of PIPAAm brush surface with various graft densities and chain lengths using the surface-initiated ATRP is an effective method for modulating thermo-responsive properties of surfaces. |
| DOI | 10.1002/mabi.201000312 |
| PMID | 21104702 |