オカノ　テルオ   OKANO Teruo   岡野　光夫    所属   研究施設 研究施設    職種   特任顧問
論文種別	原著
言語種別	英語
査読の有無	査読なし
表題	Aspects of the Belousov-Zhabotinsky Reaction inside the Self-Oscillating Polymer Brush.
掲載誌名	正式名：Langmuir : the ACS journal of surfaces and colloids 略　 称：Langmuir ISSNコード：(1520-5827)0743-7463(Linking)
掲載区分	国外
巻・号・頁	34(4),pp.1673-1680
著者・共著者	MASUDA Tsukuru†, AKIMOTO-MIZUTANI Aya, FURUSAWA Mami, TAMATE Ryota, NAGASE Kenichi, OKANO Teruo, YOSHIDA Ryo*
発行年月	2017/12
概要	We have developed a novel polymer brush surface exhibiting autonomous swelling-deswelling changes driven by the Belousov-Zhabotinsky (BZ) reaction, that is, the self-oscillating polymer brush. In this system, the ruthenium tris(2,2'-bipyridine) [Ru(bpy)3] catalyst-conjugated polymer chains are densely packed on the solid substrate. It is expected that the BZ reaction in the polymer brush would be influenced by the immobilization effect of the catalyst. To clarify the effect of immobilization of the catalyst on the self-oscillating polymer brush, the self-oscillating behavior of the polymer brush was investigated by comparing it with that of other self-oscillating polymer materials, the free polymer and the gel particle under various initial substrate concentrations. The initial substrate dependency of the oscillating period for the polymer brush was found to be different from those for the free polymer and the gel particle. Further, the oscillatory waveform was analyzed based on the Field-Körös-Noyes model. These investigations revealed that the dense immobilization of the self-oscillating polymer on the surface restricted accessibility for the Ru(bpy)3 moiety. These findings would be helpful for understanding the reaction-diffusion mechanism in the polymer brush, which is a novel reaction medium for the BZ reaction.
DOI	10.1021/acs.langmuir.7b03929
PMID	29281793