AKIYAMA Yoshikatsu
   Department   Research Institutes and Facilities, Research Institutes and Facilities
   Position   Assistant Professor
Article types Original article
Language English
Peer review Peer reviewed
Title The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite
Journal Formal name:Angewandte Chemie International Edition
Abbreviation:Angew. Chem. Inter. Ed.
ISSN code:1433-7851/1521-3773
Domestic / ForeginForegin
Publisher Wiley-VCH
Volume, Issue, Page 116(37),pp.5000-5004
Author and coauthor IKEDA Takuji, AKIYAMA Yoshikatsu, OUMI Yasunori, KAWAI Akiko, MIZUKAMI Fujio
Authorship 2nd author
Publication date 2004/09/16
Summary High‐density silicate sheets made up of five‐membered rings with Me4NOH molecules and K+ ions in the porelike interlayer space: This is the structure of the silicate PLS‐1. When PLS‐1 (left picture) was heated above 673 K under vacuum, the novel zeolite CDS‐1 (right picture) was obtained as the result of topotactic dehydration–condensation reactions. CDS‐1 is a pure silicate and thermally stable, and should therefore find a range of industrial uses.
DOI https://doi.org/10.1002/anie.200460168