アキヤマ ヨシカツ   AKIYAMA Yoshikatsu
  秋山 義勝
   所属   研究施設 研究施設
   職種   講師
論文種別 原著
言語種別 英語
査読の有無 査読あり
表題 Solvent effect on acid–base clustering between acetic acid and pyridine
掲載誌名 正式名:Journal of the Chemical Society, Perkin Transactions 2
略  称:J. Chem. Soc. Perkin Trans
ISSNコード:1472-779X
掲載区分国外
出版社 Royal Society of Chemistry
巻・号・頁 1,95-99頁
著者・共著者 AKIYAMA, Yoshikatsu, WAKISAKA Akihiro, MIZUKAMI Fujio , SAKAGUCHI Kengo
発行年月 1998
概要 The solvent effect on the acid–base interaction between acetic acid and pyridine has been studied by the mass spectrometric analysis of clusters isolated from liquid droplets. The clusters resulting from the acetic acid–pyridine, acid–base, interaction in water are quite different from those in acetonitrile solvent. In water (acetic acid∶pyridine∶water = 1∶1∶10) the acid–base interaction occurs through the intercluster interaction between acetic acid and pyridine clusters. On the other hand, in acetonitrile (acetic acid∶pyridine∶acetonitrile = 1∶1∶10), the acid–base interaction proceeds through an intermonomer interaction between an acetic acid molecule and pyridine molecule, and the clusters are produced through the aggregation of a polar (acetic acid)δ–(pyridine)δ+ complex. This solvent effect is mainly attributed to the cluster structure of acetic acid and pyridine in water and acetonitrile solvent
researchmap用URL https://researchmap.jp/y_akiyama