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アキヤマ ヨシカツ
AKIYAMA Yoshikatsu
秋山 義勝 所属 研究施設 研究施設 職種 講師 |
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| 論文種別 | 原著 |
| 言語種別 | 英語 |
| 査読の有無 | 査読あり |
| 表題 | Solvent effect on acid–base clustering between acetic acid and pyridine |
| 掲載誌名 | 正式名：Journal of the Chemical Society, Perkin Transactions 2 略 称：J. Chem. Soc. Perkin Trans ISSNコード：1472-779X |
| 掲載区分 | 国外 |
| 出版社 | Royal Society of Chemistry |
| 巻・号・頁 | 1,pp.95-99 |
| 著者・共著者 | AKIYAMA, Yoshikatsu, WAKISAKA Akihiro, MIZUKAMI Fujio , SAKAGUCHI Kengo |
| 担当区分 | 筆頭著者 |
| 発行年月 | 1998 |
| 概要 | The solvent effect on the acid–base interaction between acetic acid and pyridine has been studied by the mass spectrometric analysis of clusters isolated from liquid droplets. The clusters resulting from the acetic acid–pyridine, acid–base, interaction in water are quite different from those in acetonitrile solvent. In water (acetic acid∶pyridine∶water = 1∶1∶10) the acid–base interaction occurs through the intercluster interaction between acetic acid and pyridine clusters. On the other hand, in acetonitrile (acetic acid∶pyridine∶acetonitrile = 1∶1∶10), the acid–base interaction proceeds through an intermonomer interaction between an acetic acid molecule and pyridine molecule, and the clusters are produced through the aggregation of a polar (acetic acid)δ–(pyridine)δ+ complex. This solvent effect is mainly attributed to the cluster structure of acetic acid and pyridine in water and acetonitrile solvent |
| researchmap用URL | https://researchmap.jp/y_akiyama |