AKIYAMA Yoshikatsu
   Department   Research Institutes and Facilities, Research Institutes and Facilities
   Position   Assistant Professor
Article types Original article
Language English
Peer review Peer reviewed
Title Molecular self-assembly controlled by acid-base non-covalent interactions: A mass spectrometric study of some organic acids and bases
Journal Formal name:Journal of the Chemical Society, Faraday Transactions
Abbreviation:J. Chem. Soc. Faraday Trans.
ISSN code:0956-5000
Domestic / ForeginForegin
Publisher Royall Society of Cehmistry
Volume, Issue, Page 92,pp.3539-3544
Author and coauthor WAKISAKA Akihiro, AKIYAMA Yoshikatsu, YAMAMOTO Yoshitaka , ENGST Theo, TAKEO Harutoshi, MIZUKAMI Fujio, SAKAGUCHI Kengo, JONES Harold
Authorship 2nd author
Publication date 1996
Summary molecules provide an insight into molecular self-assembly through non-covalent interactions. The mass spectrometric analysis for the resulting clusters indicates a systematic structure change which is dependent on the acid–base interaction: a multilayer stacking structure for relatively strong acid–base pairs (phenol–pyridine, phenol–N,N-dimethylaniline, etc.), and a monolayer structure for relatively weak acid–base pairs (phenol–pyrazine, cyclohexanol–pyridine, etc.). As another viewpoint, mass spectrometry of the molecular clusters composed of acid and base molecules can be presented as a new method to characterise the acid–base interaction.
DOI 10.1039/FT9969203539
URL for researchmap https://researchmap.jp/y_akiyama