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AKIYAMA Yoshikatsu
Department Graduate School of Medical Science, Graduate School of Medical Science Position Assistant Professor |
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| Article types | Original article |
| Language | English |
| Peer review | Peer reviewed |
| Title | Molecular self-assembly controlled by acid-base non-covalent interactions: A mass spectrometric study of some organic acids and bases |
| Journal | Formal name：Journal of the Chemical Society, Faraday Transactions Abbreviation：J. Chem. Soc. Faraday Trans. ISSN code：0956-5000 |
| Domestic / Foregin | Foregin |
| Publisher | Royall Society of Cehmistry |
| Volume, Issue, Page | 92,pp.3539-3544 |
| Author and coauthor | WAKISAKA Akihiro, AKIYAMA Yoshikatsu, YAMAMOTO Yoshitaka , ENGST Theo, TAKEO Harutoshi, MIZUKAMI Fujio, SAKAGUCHI Kengo, JONES Harold |
| Authorship | 2nd author |
| Publication date | 1996 |
| Summary | molecules provide an insight into molecular self-assembly through non-covalent interactions. The mass spectrometric analysis for the resulting clusters indicates a systematic structure change which is dependent on the acid–base interaction: a multilayer stacking structure for relatively strong acid–base pairs (phenol–pyridine, phenol–N,N-dimethylaniline, etc.), and a monolayer structure for relatively weak acid–base pairs (phenol–pyrazine, cyclohexanol–pyridine, etc.). As another viewpoint, mass spectrometry of the molecular clusters composed of acid and base molecules can be presented as a new method to characterise the acid–base interaction. |
| DOI | 10.1039/FT9969203539 |
| URL for researchmap | https://researchmap.jp/y_akiyama |