アキヤマ ヨシカツ   AKIYAMA Yoshikatsu
  秋山 義勝
   所属   研究施設 研究施設
   職種   講師
論文種別 原著
言語種別 英語
査読の有無 査読あり
表題 Solvation-controlled clustering of a phenol–pyridine acid–base pair
掲載誌名 正式名:Journal of the Chemical Society, Faraday Transactions
略  称:J. Chem. Soc. Faraday Trans.
ISSNコード:0956-5000
掲載区分国外
出版社 Royal Society of Chemistry
巻・号・頁 92,3339-3346頁
著者・共著者 WAKISAKA Akihiro, YAMAMOTO Yoshitaka, AKIYAMA Yoshikatsu, TAKEO Harutoshi, MIZUKAMI Fujio, SAKAGUCHI Kengo
発行年月 1996
概要 Solvent effects on acid–base interactions between phenol and pyridine have been observed via mass spectrometry of solutions containing phenol, pyridine and water, alcohol and nitrile solvents. In the solvents having sufficiently long alkyl chains to solvate phenol and pyridine, such as propan-1-ol and propionitrile, the phenol–pyridine interaction was limited to the inter-unimolecular interactions. However, in the solvents having short alkyl chains such as methanol and acetonitrile, and in water, clustering between phenol and pyridine was observed as a result of inter-cluster interactions. The phenol molecules also formed clusters in methanol and acetonitrile, but not in propan-1-ol or propiontrile. This indicates that the observed clusters are controlled by the solvation structure depending on the solvent alkyl-chain length.
DOI 10.1039/FT9969203339
researchmap用URL https://researchmap.jp/y_akiyama