アキヤマ　ヨシカツ   Akiyama Yoshikatsu   秋山　義勝    所属   医学研究科 医学研究科 (医学部医学科をご参照ください)    職種   講師
論文種別	原著
言語種別	英語
査読の有無	査読あり
表題	Solvent effect on acid–base clustering between acetic acid and pyridine
掲載誌名	正式名：Journal of the Chemical Society, Perkin Transactions 2 略　 称：J. Chem. Soc. Perkin Trans ISSNコード：1472-779X
掲載区分	国外
出版社	Royal Society of Chemistry
巻・号・頁	1,pp.95-99
著者・共著者	AKIYAMA, Yoshikatsu, WAKISAKA Akihiro, MIZUKAMI Fujio , SAKAGUCHI Kengo
担当区分	筆頭著者
発行年月	1998
概要	The solvent effect on the acid–base interaction between acetic acid and pyridine has been studied by the mass spectrometric analysis of clusters isolated from liquid droplets. The clusters resulting from the acetic acid–pyridine, acid–base, interaction in water are quite different from those in acetonitrile solvent. In water (acetic acid∶pyridine∶water = 1∶1∶10) the acid–base interaction occurs through the intercluster interaction between acetic acid and pyridine clusters. On the other hand, in acetonitrile (acetic acid∶pyridine∶acetonitrile = 1∶1∶10), the acid–base interaction proceeds through an intermonomer interaction between an acetic acid molecule and pyridine molecule, and the clusters are produced through the aggregation of a polar (acetic acid)δ–(pyridine)δ+ complex. This solvent effect is mainly attributed to the cluster structure of acetic acid and pyridine in water and acetonitrile solvent
researchmap用URL	https://researchmap.jp/y_akiyama